New catalyst systems for iron-catalyzed hydrosilane reduction of carboxamides

Hironori Tsutsumi; Yusuke Sunada; Hideo Nagashima

doi:10.1039/c1cc10636h

New catalyst systems for iron-catalyzed hydrosilane reduction of carboxamides

Hironori Tsutsumi, Yusuke Sunada, Hideo Nagashima

分子集積化学部門

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

59 被引用数 (Scopus)

抄録

A heptanuclear iron carbonyl cluster, [Fe₃(CO) ₁₁(μ-H)]₂Fe(DMF)₄ (4), is found to be a highly efficient catalyst for the reduction of various carboxamides by 1,2-bis(dimethylsilyl)benzene (BDSB), which makes possible reducing the amount of the catalyst, shortening the reaction time, and lowering the reaction temperatures.

本文言語	英語
ページ（範囲）	6581-6583
ページ数	3
ジャーナル	Chemical Communications
巻	47
号	23
DOI	https://doi.org/10.1039/c1cc10636h
出版ステータス	出版済み - 6月 21 2011

!!!All Science Journal Classification (ASJC) codes

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学 (全般)
表面、皮膜および薄膜
金属および合金
材料化学

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title = "New catalyst systems for iron-catalyzed hydrosilane reduction of carboxamides",

abstract = "A heptanuclear iron carbonyl cluster, [Fe3(CO) 11(μ-H)]2Fe(DMF)4 (4), is found to be a highly efficient catalyst for the reduction of various carboxamides by 1,2-bis(dimethylsilyl)benzene (BDSB), which makes possible reducing the amount of the catalyst, shortening the reaction time, and lowering the reaction temperatures.",

author = "Hironori Tsutsumi and Yusuke Sunada and Hideo Nagashima",

year = "2011",

month = jun,

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doi = "10.1039/c1cc10636h",

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AU - Tsutsumi, Hironori

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AU - Nagashima, Hideo

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Y1 - 2011/6/21

N2 - A heptanuclear iron carbonyl cluster, [Fe3(CO) 11(μ-H)]2Fe(DMF)4 (4), is found to be a highly efficient catalyst for the reduction of various carboxamides by 1,2-bis(dimethylsilyl)benzene (BDSB), which makes possible reducing the amount of the catalyst, shortening the reaction time, and lowering the reaction temperatures.

AB - A heptanuclear iron carbonyl cluster, [Fe3(CO) 11(μ-H)]2Fe(DMF)4 (4), is found to be a highly efficient catalyst for the reduction of various carboxamides by 1,2-bis(dimethylsilyl)benzene (BDSB), which makes possible reducing the amount of the catalyst, shortening the reaction time, and lowering the reaction temperatures.

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New catalyst systems for iron-catalyzed hydrosilane reduction of carboxamides

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!!!All Science Journal Classification (ASJC) codes

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