New sugar-based gelators with an amino group, the gelation ability of which is remarkably reinforced by the hydrogen bond and the metal coordination

Natsuki Amanokura, Yasumasa Kanekiyo, Seiji Shinkai, David N. Reinhoudt

研究成果: ジャーナルへの寄稿学術誌査読

76 被引用数 (Scopus)

抄録

Three sugar-integrated gelators bearing a p-aminophenyl group which are expected to exert a hydrogen-bonding effect and a metal coordination effect on the gelation ability were synthesised. α-D-Galactose-based 2b was only soluble or precipitated and β-D-glucose-based 4b gelated only two of 15 solvents tested herein whereas α-D-glucose-based 1b acted as an excellent gelator which could gelate 8 solvents. The sol - gel phase-transition temperature (Tgel) values for 1b were higher by 41-78 °C than those for α-D-glucose-based 1a bearing a p-nitrophenyl group. The spectral studies indicated that this gel reinforcement is due to the hydrogen-bonding interaction including the amino group. The Tgel values for the ethanol gel of 1b were markedly improved by the addition of AgNO3, CoCl2 or CdCl2. The detailed examination of a 1b + CoCl2 gel system in ethanol showed that the gel is stabilised by the 'cross-link' of 1b molecules by the Co(II) - amino group interaction. This is the first and a convenient method for the metal reinforcement of organic gels.

本文言語英語
ページ(範囲)1995-2000
ページ数6
ジャーナルJournal of the Chemical Society. Perkin Transactions 2
10
DOI
出版ステータス出版済み - 1月 1 1999
外部発表はい

!!!All Science Journal Classification (ASJC) codes

  • 化学 (全般)

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