New water-soluble host molecules derived from calix[6]arene

Seiji Shinkai, Seiichi Mori, Takayuki Tsubaki, Takaaki Sone, Osamu Manabe

研究成果: Contribution to journalArticle査読

200 被引用数 (Scopus)

抄録

4-Sulfonate derivatives of calix[6]arene and O-n-hexylcalix[6]arene (1a and 1b, respectively) were synthesized. Measurements using fluorescence and absorption spectral probes indicated that the cavity of calix-[6]arene can accept a naphthalene molecule but not a pyrene molecule and that (1b) has a hydrophobic cavity constructed from the aggregate of the hexyl groups while (1a) provides a reaction field apparently more polar than water. This is the first example for water-soluble host molecules derived from calix[6]arene.

本文言語英語
ページ(範囲)5315-5318
ページ数4
ジャーナルTetrahedron Letters
25
46
DOI
出版ステータス出版済み - 1984
外部発表はい

All Science Journal Classification (ASJC) codes

  • 生化学
  • 創薬
  • 有機化学

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