A paper-structured catalyst (PSC) for biogas reforming was prepared with the aim of improving coking tolerance. During the paper-making process using inorganic fibers, Ni-loaded (Ce,Zr)O2–δ particles were synthesized via co-precipitation and subsequent chemical reduction (on-paper synthesis). The effects of the CeO2/ZrO2 weight ratio during preparation and the Ni loading amount on the catalytic activity for dry reforming of CH4 were investigated at 750 °C. A Ni loading of 6 wt% with CeO2/ZrO2 ≥ 1 led to stable CH4 conversion of 85% without coking under a gas hourly space velocity of 3800 h−1. The oxygen storage capacity of the (Ce,Zr)O2–δ particles dispersed in the inorganic fiber network may contribute to the oxidation of carbonaceous species deposited on the catalyst surface.
!!!All Science Journal Classification (ASJC) codes