Nickel-catalyzed formation of a carbon-nitrogen bond at the β position of saturated ketones

Satoshi Ueno, Ryosuke Shimizu, Ryoichi Kuwano

研究成果: ジャーナルへの寄稿記事

62 引用 (Scopus)

抄録

Gone fishing: When propiophenone and related ethyl ketones are treated with morpholine in the presence of K3PO4, chlorobenzene, and [Ni(cod)2]/PMe3 catalyst, a carbon-nitrogen bond is formed selectively at the β position (see scheme; cod=cycloocta-1,5-diene). Secondary amines were employed as substrates to give the corresponding β- enaminones.

元の言語英語
ページ(範囲)4543-4545
ページ数3
ジャーナルAngewandte Chemie - International Edition
48
発行部数25
DOI
出版物ステータス出版済み - 6 8 2009

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Propiophenones
Nickel
Ketones
Amines
Nitrogen
Carbon
Catalysts
Substrates
chlorobenzene
morpholine

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Catalysis

これを引用

Nickel-catalyzed formation of a carbon-nitrogen bond at the β position of saturated ketones. / Ueno, Satoshi; Shimizu, Ryosuke; Kuwano, Ryoichi.

:: Angewandte Chemie - International Edition, 巻 48, 番号 25, 08.06.2009, p. 4543-4545.

研究成果: ジャーナルへの寄稿記事

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