Nickel(II), Palladium(II), and Platinum(II) η3-Allyl Complexes Bearing a Bidentate Titanium(IV) Phosphinoamide Ligand: A Ti←M2 Dative Bond Enhances the Electrophilieity of the π-Allyl

Hironori Tsutsumi, Yusuke Sunada, Yoshihito Shiota, Kazunari Yoshizawa, Hideo Nagashima

研究成果: ジャーナルへの寄稿記事

42 引用 (Scopus)

抄録

Three Ti-M2 (M2 = Ni, Pd, Pt) heterobimetallic complexes, [η3-methallyl)M2(Ph2PN tBu)2TiCl2](OTf), were synthesized in which a TiIV←M2 interaction was suggested by crystallography and DFT calculations. The TiIV←M2 interaction enhanced electrophilicity of the η3-methallyl ligand of M 2, leading to high reactivity of the η3-methallyl moiety with Et2NH compared with that of the dppp analogue.

元の言語英語
ページ(範囲)1988-1991
ページ数4
ジャーナルOrganometallics
28
発行部数7
DOI
出版物ステータス出版済み - 4 13 2009

Fingerprint

Bearings (structural)
Crystallography
Palladium
Titanium
Platinum
Nickel
Discrete Fourier transforms
palladium
platinum
titanium
nickel
Ligands
ligands
crystallography
reactivity
interactions
analogs

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

これを引用

@article{2b4b34cd7b48422888698aba61c4568c,
title = "Nickel(II), Palladium(II), and Platinum(II) η3-Allyl Complexes Bearing a Bidentate Titanium(IV) Phosphinoamide Ligand: A Ti←M2 Dative Bond Enhances the Electrophilieity of the π-Allyl",
abstract = "Three Ti-M2 (M2 = Ni, Pd, Pt) heterobimetallic complexes, [η3-methallyl)M2(Ph2PN tBu)2TiCl2](OTf), were synthesized in which a TiIV←M2 interaction was suggested by crystallography and DFT calculations. The TiIV←M2 interaction enhanced electrophilicity of the η3-methallyl ligand of M 2, leading to high reactivity of the η3-methallyl moiety with Et2NH compared with that of the dppp analogue.",
author = "Hironori Tsutsumi and Yusuke Sunada and Yoshihito Shiota and Kazunari Yoshizawa and Hideo Nagashima",
year = "2009",
month = "4",
day = "13",
doi = "10.1021/om8011085",
language = "English",
volume = "28",
pages = "1988--1991",
journal = "Organometallics",
issn = "0276-7333",
publisher = "American Chemical Society",
number = "7",

}

TY - JOUR

T1 - Nickel(II), Palladium(II), and Platinum(II) η3-Allyl Complexes Bearing a Bidentate Titanium(IV) Phosphinoamide Ligand

T2 - A Ti←M2 Dative Bond Enhances the Electrophilieity of the π-Allyl

AU - Tsutsumi, Hironori

AU - Sunada, Yusuke

AU - Shiota, Yoshihito

AU - Yoshizawa, Kazunari

AU - Nagashima, Hideo

PY - 2009/4/13

Y1 - 2009/4/13

N2 - Three Ti-M2 (M2 = Ni, Pd, Pt) heterobimetallic complexes, [η3-methallyl)M2(Ph2PN tBu)2TiCl2](OTf), were synthesized in which a TiIV←M2 interaction was suggested by crystallography and DFT calculations. The TiIV←M2 interaction enhanced electrophilicity of the η3-methallyl ligand of M 2, leading to high reactivity of the η3-methallyl moiety with Et2NH compared with that of the dppp analogue.

AB - Three Ti-M2 (M2 = Ni, Pd, Pt) heterobimetallic complexes, [η3-methallyl)M2(Ph2PN tBu)2TiCl2](OTf), were synthesized in which a TiIV←M2 interaction was suggested by crystallography and DFT calculations. The TiIV←M2 interaction enhanced electrophilicity of the η3-methallyl ligand of M 2, leading to high reactivity of the η3-methallyl moiety with Et2NH compared with that of the dppp analogue.

UR - http://www.scopus.com/inward/record.url?scp=65349099949&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=65349099949&partnerID=8YFLogxK

U2 - 10.1021/om8011085

DO - 10.1021/om8011085

M3 - Article

AN - SCOPUS:65349099949

VL - 28

SP - 1988

EP - 1991

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 7

ER -