[N,N′-bis(2-aminoethyl-κN)-N,N′-bis(2-ammonioethyl) ethylenediamine-κ2N,N′]-platinum(II) bis(tetrachloroplatinate) trihydrate

Ken Sakai, Yuko Tanaka, Taro Tsubomura

研究成果: ジャーナルへの寄稿記事

6 引用 (Scopus)

抄録

The reaction between K2PtCl4 and penten [N,N,N′,N′-tetrakis(2-aminoethyl)ethylenediamine] gave a Magnus-type double salt, [Pt(C10H30N6)][PtCl4] 2.3H2O, in which the diprotonated penten ligand (pentenH2) serves as a tetradentate chelating ligand. The complex involves an ion pair, {[Pt(pentenH2)][PtCl4]}2+. These two mononuclear units have an attractive interaction for each other, with several hydrogen bonds formed between the amine groups and Cl atoms. The two Pt atoms are shifted out of their ideal coordination planes towards each other and the Pt⋯Pt distance within this unit is 3.414 (3) Å.

元の言語英語
ページ(範囲)541-543
ページ数3
ジャーナルActa Crystallographica Section C: Crystal Structure Communications
52
発行部数3
DOI
出版物ステータス出版済み - 3 15 1996
外部発表Yes

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ethylenediamine
Platinum
Ligands
Atoms
Chelation
Amines
Hydrogen
Hydrogen bonds
Salts
Ions
tetrachloroplatinate
platinum tetrachloride

All Science Journal Classification (ASJC) codes

  • Biochemistry, Genetics and Molecular Biology(all)

これを引用

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title = "[N,N′-bis(2-aminoethyl-κN)-N,N′-bis(2-ammonioethyl) ethylenediamine-κ2N,N′]-platinum(II) bis(tetrachloroplatinate) trihydrate",
abstract = "The reaction between K2PtCl4 and penten [N,N,N′,N′-tetrakis(2-aminoethyl)ethylenediamine] gave a Magnus-type double salt, [Pt(C10H30N6)][PtCl4] 2.3H2O, in which the diprotonated penten ligand (pentenH2) serves as a tetradentate chelating ligand. The complex involves an ion pair, {[Pt(pentenH2)][PtCl4]}2+. These two mononuclear units have an attractive interaction for each other, with several hydrogen bonds formed between the amine groups and Cl atoms. The two Pt atoms are shifted out of their ideal coordination planes towards each other and the Pt⋯Pt distance within this unit is 3.414 (3) {\AA}.",
author = "Ken Sakai and Yuko Tanaka and Taro Tsubomura",
year = "1996",
month = "3",
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language = "English",
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pages = "541--543",
journal = "Acta Crystallographica Section C: Crystal Structure Communications",
issn = "0108-2701",
publisher = "International Union of Crystallography",
number = "3",

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TY - JOUR

T1 - [N,N′-bis(2-aminoethyl-κN)-N,N′-bis(2-ammonioethyl) ethylenediamine-κ2N,N′]-platinum(II) bis(tetrachloroplatinate) trihydrate

AU - Sakai, Ken

AU - Tanaka, Yuko

AU - Tsubomura, Taro

PY - 1996/3/15

Y1 - 1996/3/15

N2 - The reaction between K2PtCl4 and penten [N,N,N′,N′-tetrakis(2-aminoethyl)ethylenediamine] gave a Magnus-type double salt, [Pt(C10H30N6)][PtCl4] 2.3H2O, in which the diprotonated penten ligand (pentenH2) serves as a tetradentate chelating ligand. The complex involves an ion pair, {[Pt(pentenH2)][PtCl4]}2+. These two mononuclear units have an attractive interaction for each other, with several hydrogen bonds formed between the amine groups and Cl atoms. The two Pt atoms are shifted out of their ideal coordination planes towards each other and the Pt⋯Pt distance within this unit is 3.414 (3) Å.

AB - The reaction between K2PtCl4 and penten [N,N,N′,N′-tetrakis(2-aminoethyl)ethylenediamine] gave a Magnus-type double salt, [Pt(C10H30N6)][PtCl4] 2.3H2O, in which the diprotonated penten ligand (pentenH2) serves as a tetradentate chelating ligand. The complex involves an ion pair, {[Pt(pentenH2)][PtCl4]}2+. These two mononuclear units have an attractive interaction for each other, with several hydrogen bonds formed between the amine groups and Cl atoms. The two Pt atoms are shifted out of their ideal coordination planes towards each other and the Pt⋯Pt distance within this unit is 3.414 (3) Å.

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U2 - 10.1107/S0108270195011413

DO - 10.1107/S0108270195011413

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JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

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