[N,N′-bis(2-aminoethyl-κN)-N,N′-bis(2-ammonioethyl) ethylenediamine-κ2N,N′]-platinum(II) bis(tetrachloroplatinate) trihydrate

Ken Sakai, Yuko Tanaka, Taro Tsubomura

研究成果: Contribution to journalArticle査読

6 被引用数 (Scopus)

抄録

The reaction between K2PtCl4 and penten [N,N,N′,N′-tetrakis(2-aminoethyl)ethylenediamine] gave a Magnus-type double salt, [Pt(C10H30N6)][PtCl4] 2.3H2O, in which the diprotonated penten ligand (pentenH2) serves as a tetradentate chelating ligand. The complex involves an ion pair, {[Pt(pentenH2)][PtCl4]}2+. These two mononuclear units have an attractive interaction for each other, with several hydrogen bonds formed between the amine groups and Cl atoms. The two Pt atoms are shifted out of their ideal coordination planes towards each other and the Pt⋯Pt distance within this unit is 3.414 (3) Å.

本文言語英語
ページ(範囲)541-543
ページ数3
ジャーナルActa Crystallographica Section C: Crystal Structure Communications
52
3
DOI
出版ステータス出版済み - 3 15 1996
外部発表はい

All Science Journal Classification (ASJC) codes

  • Biochemistry, Genetics and Molecular Biology(all)

フィンガープリント 「[N,N′-bis(2-aminoethyl-κN)-N,N′-bis(2-ammonioethyl) ethylenediamine-κ<sup>2</sup>N,N′]-platinum(II) bis(tetrachloroplatinate) trihydrate」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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