TY - JOUR
T1 - Non-equilibrium origin of high electrical conductivity in gallium zinc oxide thin films
AU - Zakutayev, Andriy
AU - Perry, Nicola H.
AU - Mason, Thomas O.
AU - Ginley, David S.
AU - Lany, Stephan
N1 - Funding Information:
This research was supported by the U.S. Department of Energy under Contract No. DE-AC36-08GO28308 to the National Renewable Energy Laboratory (NREL). The theoretical calculations and the thin film experiments were supported by the Office of Energy Efficiency and Renewable Energy, Solar Energy Technology Program. The in-situ van der Pauw measurements were supported by the Office of Science, Basic Energy Science Program, as a part of the Energy Frontier Research Center “Center for Inverse Design”. Useful discussions with P. F. Ndione, A. Adler, and J. D. Perkins are gratefully acknowledged.
PY - 2013/12/2
Y1 - 2013/12/2
N2 - Non-equilibrium state defines physical properties of materials in many technologies, including architectural, metallic, and semiconducting amorphous glasses. In contrast, crystalline electronic and energy materials, such as transparent conductive oxides (TCO), are conventionally thought to be in equilibrium. Here, we demonstrate that high electrical conductivity of crystalline Ga-doped ZnO TCO thin films occurs by virtue of metastable state of their defects. These results imply that such defect metastability may be important in other functional oxides. This finding emphasizes the need to understand and control non-equilibrium states of materials, in particular, their metastable defects, for the design of novel functional materials.
AB - Non-equilibrium state defines physical properties of materials in many technologies, including architectural, metallic, and semiconducting amorphous glasses. In contrast, crystalline electronic and energy materials, such as transparent conductive oxides (TCO), are conventionally thought to be in equilibrium. Here, we demonstrate that high electrical conductivity of crystalline Ga-doped ZnO TCO thin films occurs by virtue of metastable state of their defects. These results imply that such defect metastability may be important in other functional oxides. This finding emphasizes the need to understand and control non-equilibrium states of materials, in particular, their metastable defects, for the design of novel functional materials.
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U2 - 10.1063/1.4841355
DO - 10.1063/1.4841355
M3 - Article
AN - SCOPUS:84889792512
SN - 0003-6951
VL - 103
JO - Applied Physics Letters
JF - Applied Physics Letters
IS - 23
M1 - 232106
ER -