Non-Precious-Metal Catalytic Systems Involving Iron or Cobalt Carboxylates and Alkyl Isocyanides for Hydrosilylation of Alkenes with Hydrosiloxanes

Daisuke Noda, Atsushi Tahara, Yusuke Sunada, Hideo Nagashima

研究成果: Contribution to journalArticle査読

117 被引用数 (Scopus)

抄録

A mixture of an iron or a cobalt carboxylate and an isocyanide ligand catalyzed the hydrosilylation of alkenes with hydrosiloxanes with high efficiency (TON >103) and high selectivity. The Fe catalyst showed excellent activity for hydrosilylation of styrene derivatives, whereas the Co catalyst was widely effective in reaction of alkenes. Both of them catalyzed the reaction with allylic ethers. Chemical modification and cross-linking of silicones were achieved by choosing the right catalyst and reaction conditions.

本文言語英語
ページ(範囲)2480-2483
ページ数4
ジャーナルJournal of the American Chemical Society
138
8
DOI
出版ステータス出版済み - 3 2 2016

All Science Journal Classification (ASJC) codes

  • 触媒
  • 化学 (全般)
  • 生化学
  • コロイド化学および表面化学

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