Nonanuclear Ni(II) complexes in a [1-7-1] formation derived from asymmetric multidentate ligands

Magnetic and electrochemical properties

Yasuhiro Tsuji, Tatsuo Togo, Akio Mishima, Tomomi Koshiyama, Masaaki Ohba

研究成果: ジャーナルへの寄稿記事

抄録

Nonanuclear Ni(ii) complexes, [Ni9(Ln)6(OH)6(H2O)6] (Ni9Ln, n = 1-4; H2Ln = 6-acetoacetyl-2-pyridinecarboxylic acid derivatives), were prepared via self-assembly using the asymmetric multidentate ligands H2Ln. A corner-sharing tetrahedron-type structure, [Ni73-OH)6]8+, and terminal mononuclear units constitute the nonanuclear structure in a [1-7-1] formation. The electrochemical and magnetic properties of Ni9Ln were modulated by the introduction of various substituents in H2Ln.

元の言語英語
ページ(範囲)4036-4039
ページ数4
ジャーナルDalton Transactions
47
発行部数12
DOI
出版物ステータス出版済み - 1 1 2018

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Electrochemical properties
Self assembly
Magnetic properties
Ligands
Derivatives
picolinic acid

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

これを引用

Nonanuclear Ni(II) complexes in a [1-7-1] formation derived from asymmetric multidentate ligands : Magnetic and electrochemical properties. / Tsuji, Yasuhiro; Togo, Tatsuo; Mishima, Akio; Koshiyama, Tomomi; Ohba, Masaaki.

:: Dalton Transactions, 巻 47, 番号 12, 01.01.2018, p. 4036-4039.

研究成果: ジャーナルへの寄稿記事

Tsuji, Yasuhiro ; Togo, Tatsuo ; Mishima, Akio ; Koshiyama, Tomomi ; Ohba, Masaaki. / Nonanuclear Ni(II) complexes in a [1-7-1] formation derived from asymmetric multidentate ligands : Magnetic and electrochemical properties. :: Dalton Transactions. 2018 ; 巻 47, 番号 12. pp. 4036-4039.
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