Novel fluorinated polymer from 18-crown-6 by radical polyaddition

Tadashi Narita, Hiroshi Hamana, Masato Takeshita, Hirotada Fujiwara

研究成果: Contribution to journalArticle査読

9 被引用数 (Scopus)

抄録

Radical polyaddition of bis(α-trifluoromethyl-β, β-difluorovinyl) terephthalate [CF2=C (CF3)OCOC6H4COOC(CF3) =CF2] (BFP) with 18-crown-6 to produce fluorinated polymer bearing crown ether moiety in main chain is described. Prior to polyaddition, the model reaction of 2-benzoxypentafluoropropene [CF2=C(CF3)OCOC6H5] (BPFP) with 18-crown-6 was investigated to afford suitable reactions condition for polyaddition. The polyaddition of BFP with 18-crown-6 yielded a soluble polymer bearing Mn=5.5×104 with unimodal molecular weight distribution after purification by reprecipitation with cold ethanol.

本文言語英語
ページ(範囲)197-201
ページ数5
ジャーナルJournal of Fluorine Chemistry
124
2
DOI
出版ステータス出版済み - 12 3 2003
外部発表はい

All Science Journal Classification (ASJC) codes

  • 生化学
  • 環境化学
  • 物理化学および理論化学
  • 有機化学
  • 無機化学

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