Numerical simulation of elution chromatography for separation of H2-HD- D2 mixtures using a palladium particle bed

Satoshi Fukada

研究成果: ジャーナルへの寄稿記事

4 引用 (Scopus)

抄録

Elution chromatography for hydrogen isotope separation is numerically analyzed under conditions where a H2-HD-D2 mixture is injected into a palladium particle bed followed by an inert gas purge. When an isotopic mixture of a nearly equal atomic molar fraction of protium and deuterium is developed in the bed with an inert gas purge, effluent concentration bands of each hydrogen species exhibit several characteristics different from ones expected from the Gaussian distribution function. The characteristics are a D2 band with the highest peak, a HD band with a moderate peak, and a H2 band drawing a broader or plateau-like curve and having a shoulder around its back end. They are well revealed by the present calculation model. The calculation model is applied to elution chromatography of the six-component hydrogen isotopes using a Pd bed to simulate the isotope separation system of an experimental fusion reactor.

元の言語英語
ページ(範囲)2699-2721
ページ数23
ジャーナルSeparation Science and Technology
34
発行部数14
DOI
出版物ステータス出版済み - 12 1 1999

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Palladium
Chromatography
Isotopes
Noble Gases
Hydrogen
Inert gases
Computer simulation
Deuterium
Fusion reactors
Gaussian distribution
Distribution functions
Effluents

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)
  • Process Chemistry and Technology
  • Filtration and Separation

これを引用

Numerical simulation of elution chromatography for separation of H2-HD- D2 mixtures using a palladium particle bed. / Fukada, Satoshi.

:: Separation Science and Technology, 巻 34, 番号 14, 01.12.1999, p. 2699-2721.

研究成果: ジャーナルへの寄稿記事

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