Observation of orientation-dependent CF3 chemiluminescence in the reaction of Ar(3P0,2) with oriented CF3H

Hiroshi Ohoyama, Toshio Kasai, Kazuhiko Ohashi, Keiji Kuwata

研究成果: Contribution to journalArticle査読

14 被引用数 (Scopus)

抄録

Orientation-dependent CF3 chemiluminescence from 430 to 930 nm was observed for the first time in the reaction of pulsed supersonic molecular beams of metastable argon atoms and oriented CF3H molecules. The "sideways configuration" of CF3H as well as the "F-end configuration" was found to be more reactive than the "H-end configuration". The Legendre expansion technique of Stolte et al. was applied up to the fourth term. A dissimilar dependence of reactivity on molecular orientation for the UV emission of CF3 was also indicated from the present experiment.

本文言語英語
ページ(範囲)236-240
ページ数5
ジャーナルChemical Physics Letters
136
3-4
DOI
出版ステータス出版済み - 5 8 1987
外部発表はい

All Science Journal Classification (ASJC) codes

  • 物理学および天文学(全般)
  • 物理化学および理論化学

フィンガープリント

「Observation of orientation-dependent CF<sub>3</sub> chemiluminescence in the reaction of Ar(<sup>3</sup>P<sub>0,2</sub>) with oriented CF<sub>3</sub>H」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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