Observation of the chemical reaction equilibria of element 104, rutherfordium: Solid-liquid extraction of Rf, Zr, Hf and Th with Aliquat 336 resin from HCl

Takuya Yokokita, Yoshitaka Kasamatsu, Aiko Kino, Hiromitsu Haba, Yudai Shigekawa, Yuki Yasuda, Kouhei Nakamura, Keigo Toyomura, Yukiko Komori, Masashi Murakami, Takashi Yoshimura, Naruto Takahashi, Kosuke Morita, Atsushi Shinohara

研究成果: Contribution to journalArticle査読

2 被引用数 (Scopus)

抄録

We successfully observed the equilibrium state of the chemical reactions for superheavy elements on a one-atom-at-a-time scale; we investigated the time dependence of the extraction behaviour of element 104, Rf. The distribution coefficient of Rf in 9 M HCl was found to be higher than those of its homologous elements, probably due to differences in the chloride complexation of Rf.

本文言語英語
ページ(範囲)18827-18831
ページ数5
ジャーナルDalton Transactions
45
47
DOI
出版ステータス出版済み - 2016
外部発表はい

All Science Journal Classification (ASJC) codes

  • 無機化学

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