Octahedral morphology of NiO with (111) facet synthesized from the transformation of NiOHCl for the NO: Xdetection and degradation: Experiment and DFT calculation

Angga Hermawan, Adie Tri Hanindriyo, Erland Rachmad Ramadhan, Yusuke Asakura, Takuya Hasegawa, Kenta Hongo, Miki Inada, Ryo Maezono, Shu Yin

研究成果: Contribution to journalArticle査読

抄録

Nitrogen oxides (NOx) are poisonous gases to humans and environment, and need to be monitored at an early stage. Accordingly, the design of facets on metal oxide semiconductors is an efficient approach to boost their gas sensing and photocatalytic performances due to the desirable active sites. However, in a rock-type structured NiO, a highly polar (111) exposed facets cannot be easily exposed due to their unfavorable thermodynamics. Herein, we demonstrate the synthesis of NiO with a dominant (111) facet from the transformation of NiOHCl with a layered structure. Among the crystal facets, NiO-Octa (111) exhibited the best NOx gas sensing response (16.5%) to the 300 ppb level and deNOx photocatalytic ability of over 50% under UV irradiation. DFT calculations revealed that the abundance of Ni atoms in the clean (111) surface layer allow the favorable adsorption of N adatoms, forming the Ni-N bond. The charge transfer occurring from NiO to the NO orbital was proven to be the cause for bond weakening and stretching from 1.1692 Å to 1.2231 Å, leading to NOx molecular decomposition, consistent with experimental results. This journal is

本文言語英語
ページ(範囲)3431-3442
ページ数12
ジャーナルInorganic Chemistry Frontiers
7
18
DOI
出版ステータス出版済み - 9 21 2020

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

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