Odor sensors based on molecular wire and nanofibers

Kenshi Hayashi, Chuanjun Liu

研究成果: Chapter in Book/Report/Conference proceedingChapter

抄録

Chemical sensors that can be applied for an odor sensing must detect a very small portion of the bulk adsorbent. In order to realize this point it is necessary to observe an interaction between analytes and sensor surfaces sensitively. A candidate to achieve such chemical sensing is a switching behavior of a functional molecular that occurs on conductive molecules by adsorbing chemicals. If the electronic properties of the molecule are affected by such switching behavior, conductance will be easily changed. A charge transfer (CT) interaction between chemicals is a general concept for the conductance change, in which doping effect that causes donor or acceptor, Coulomb repulsion by electron correlation, or acid base reaction affects electrical conductance of materials. In the most typical case appeared in low dimensional conduct, CT interaction causes insulator-conductor transition, e.g., Mott transition, of materials, i.e., molecular switching phenomena. On the other hand, a nanostructured sensor surface is necessary to detect molecular conductance change caused by tiny analytes adsorption. In this study, we suggest sensor investigation for various volatile compounds by a transition of molecular wire conductance induced by electron-correlation interaction formation.

本文言語英語
ホスト出版物のタイトルBiochemical Sensors
ホスト出版物のサブタイトルMimicking Gustatory and Olfactory Senses
出版社Pan Stanford Publishing Pte. Ltd.
ページ305-319
ページ数15
ISBN(電子版)9789814303422
ISBN(印刷版)9789814267076
DOI
出版ステータス出版済み - 9 23 2013

All Science Journal Classification (ASJC) codes

  • 医学(全般)
  • 生化学、遺伝学、分子生物学(全般)
  • 化学 (全般)
  • 化学工学(全般)
  • 工学(全般)
  • 物理学および天文学(全般)

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