Olefin metathesis of the aligned assemblies of conjugated polymers constructed through supramolecular bundling

Rie Wakabayashi, Yohei Kubo, Kenji Kaneko, Masayuki Takeuchi, Seiji Shinkai

研究成果: ジャーナルへの寄稿学術誌査読

29 被引用数 (Scopus)

抄録

The ordered structures constructed from an aligner molecule 1o and conjugated polymers (CPs) were efficiently converted into the poly-pseudo-rotaxane structures by the template-assisted ring-closing olefin metathesis (RCM) of olefinic groups at the peripheral positions of 1o. Moreover, the poly-pseudo-rotaxane structures permitted the separation of the crystalline ordered assemblies of CP by size exclusion chromatography and the preservation of the sheet morphologies after the treatment with trifluoroacetic acid. The morphologies and the periodicities of assemblies were also maintained after the retrieving treatments.

本文言語英語
ページ(範囲)8744-8745
ページ数2
ジャーナルJournal of the American Chemical Society
128
27
DOI
出版ステータス出版済み - 7月 12 2006

!!!All Science Journal Classification (ASJC) codes

  • 触媒
  • 化学 (全般)
  • 生化学
  • コロイド化学および表面化学

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