Oligomerization of butadiene with (η-C5R5)RuII complexes; stoichiometric and catalytic chemistry

Katsuyuki Masuda, Katsumasa Nakano, Takahiko Fukahori, Hideo Nagashima, Kenji Itoh

研究成果: ジャーナルへの寄稿学術誌査読

16 被引用数 (Scopus)

抄録

Treatment of (η-C5R5)Ru(η-butadiene)X; (R H, Me; X Br, Cl) with butadiene, in the presence of silver triflate, yielded cationic complexes with 1,3,7-octatriene ligands, produced from the CC bond formation at both the terminal carbon atoms of two molecules of butadiene. In the pentamethylcyclopentadienyl system the octatriene ligand was cyclodimerized to 1,5-cyclooctadiene when treated with carbon monoxide. The ligand structure was elucidated by NMR spectroscopy. Catalytic reactions on these systems have also been studied.

本文言語英語
ページ(範囲)C21-C24
ジャーナルJournal of Organometallic Chemistry
428
1-2
DOI
出版ステータス出版済み - 4月 28 1992
外部発表はい

!!!All Science Journal Classification (ASJC) codes

  • 生化学
  • 物理化学および理論化学
  • 有機化学
  • 無機化学
  • 材料化学

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