One-pot synthesis of 2,5-diformylfuran from carbohydrate derivatives by sulfonated resin and hydrotalcite-supported ruthenium catalysts

Atsushi Takagaki, Miho Takahashi, Shun Nishimura, Kohki Ebitani

研究成果: Contribution to journalArticle査読

193 被引用数 (Scopus)

抄録

2,5-Diformylfuran (DFF) was selectively synthesized from 5-hydroxymethylfurfural using a hydrotalcite-supported ruthenium catalyst (Ru/HT) by oxidation with molecular oxygen under mild reaction conditions. A combination of hydrotalcite, Amberlyst-15, and Ru/HT catalysts successfully afforded direct synthesis of DFF from hexoses such as fructose and glucose via isomerization, dehydration, and successive selective oxidation in one pot. Stepwise addition of catalyst improved DFF yield up to 49% from fructose and 25% from glucose, respectively.

本文言語英語
ページ(範囲)1562-1565
ページ数4
ジャーナルACS Catalysis
1
11
DOI
出版ステータス出版済み - 11 4 2011
外部発表はい

All Science Journal Classification (ASJC) codes

  • 触媒
  • 化学 (全般)

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