One-Pot Synthesis of Tertiary Amides from Organic Trichlorides through Oxygen Atom Incorporation from Air by Convergent Paired Electrolysis

研究成果: Contribution to journalArticle査読

2 被引用数 (Scopus)

抄録

A convergent paired electrolysis catalyzed by a B12 complex for the one-pot synthesis of a tertiary amide from organic trichlorides (R-CCl3) has been developed. Various readily available organic trichlorides, such as benzotrichloride and its derivatives, chloroform, dichlorodiphenyltrichloroethane (DDT), trichloro-2,2,2-trifluoroethane (CFC-113a), and trichloroacetonitrile (CNCCl3), were converted to amides in the presence of tertiary amines through oxygen incorporation from air at room temperature. The amide formation mechanism in the paired electrolysis, which was mediated by a cobalt complex, was proposed.

本文言語英語
ページ(範囲)5983-5990
ページ数8
ジャーナルJournal of Organic Chemistry
86
8
DOI
出版ステータス出版済み - 4 16 2021

All Science Journal Classification (ASJC) codes

  • 有機化学

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