One-shot-laser-pulse-induced cooperative charge transfer accompanied by spin transition in a Co-Fe prussian blue analog at room temperature

Naonobu Shimamoto; Shin ichi Ohkoshi; Osamu Sato; Kazuhito Hashimoto

doi:10.1246/cl.2002.486

One-shot-laser-pulse-induced cooperative charge transfer accompanied by spin transition in a Co-Fe prussian blue analog at room temperature

Naonobu Shimamoto, Shin ichi Ohkoshi, Osamu Sato, Kazuhito Hashimoto

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

44 被引用数 (Scopus)

抄録

A one-shot-laser-pulse (6 ns) irradiation converted the electronic state of Na_0.68Co_1.20[Fe(CN)₆]· 3.7H₂O from Fe^II(S = 0)-CN-Co^III(S = 0) to Fe^III(S = 1/2)-CN-Co^II(S = 3/2) at room temperature. This photochemical reaction was observed only above the power density of 45 mJ pulse^-1 cm^-2, and its quantum yield amounted to about 200%.

本文言語	英語
ページ（範囲）	486-487
ページ数	2
ジャーナル	Chemistry Letters
号	4
DOI	https://doi.org/10.1246/cl.2002.486
出版ステータス	出版済み - 4月 5 2002
外部発表	はい

!!!All Science Journal Classification (ASJC) codes

化学 (全般)

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10.1246/cl.2002.486

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引用スタイル

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abstract = "A one-shot-laser-pulse (6 ns) irradiation converted the electronic state of Na0.68Co1.20[Fe(CN)6]· 3.7H2O from FeII(S = 0)-CN-CoIII(S = 0) to FeIII(S = 1/2)-CN-CoII(S = 3/2) at room temperature. This photochemical reaction was observed only above the power density of 45 mJ pulse-1 cm-2, and its quantum yield amounted to about 200%.",

author = "Naonobu Shimamoto and Ohkoshi, {Shin ichi} and Osamu Sato and Kazuhito Hashimoto",

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AU - Shimamoto, Naonobu

AU - Ohkoshi, Shin ichi

AU - Sato, Osamu

AU - Hashimoto, Kazuhito

PY - 2002/4/5

Y1 - 2002/4/5

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AB - A one-shot-laser-pulse (6 ns) irradiation converted the electronic state of Na0.68Co1.20[Fe(CN)6]· 3.7H2O from FeII(S = 0)-CN-CoIII(S = 0) to FeIII(S = 1/2)-CN-CoII(S = 3/2) at room temperature. This photochemical reaction was observed only above the power density of 45 mJ pulse-1 cm-2, and its quantum yield amounted to about 200%.

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