One-step synthesis of hyper-branched polymer with perfluoroalkyl segments

Masayuki Haraguchi, Tomoyasu Hirai, Masahiro Ozawa, Misao Miyamoto, Keiji Tanaka

研究成果: Contribution to journalArticle査読

2 被引用数 (Scopus)

抄録

Initiator-fragment incorporation radical polymerization (IFIRP) of commercially available fluorinated monomers was performed in the presence of cross-linking agents, resulting in a hyperbranched polymer with perfluoroalkyl groups (F-HBP). In our one-step method, a F-HBP was successfully prepared without gelation within 1 h. The FHBP exhibited interesting properties based on both the hyperbranched architecture and the perfluoroalkyl groups, such as good solubility in common organic solvents, high thermal stability, and low surface free energy.

本文言語英語
ページ(範囲)34-38
ページ数5
ジャーナルKGK Kautschuk Gummi Kunststoffe
65
7-8
出版ステータス出版済み - 7 1 2012

All Science Journal Classification (ASJC) codes

  • 機械工学
  • ポリマーおよびプラスチック
  • 産業および生産工学
  • 材料化学

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