One-step synthesis of micro-/mesoporous SnO2 spheres by solvothermal method for toluene gas sensor

Angga Hermawan, Yusuke Asakura, Miki Inada, Shu Yin

研究成果: ジャーナルへの寄稿記事

抄録

A facile solvothermal synthesis in an ethanol/acetic acid mixture for the fabrication of SnO2 with a controllable hierarchical spherical size and micro-/mesoporosity is presented. SEM, TEM and N2 adsorption/desorption investigation unveiled that the obtained SnO2 spheres exhibited a particle size in the range of 0.6–1.6 μm and a pore size of about 1.4–1.9 nm depending on the volume ratio of acetic acid to ethanol in the reaction mixture, and the spheres were constructed by nanoscale particles. Due to its micro-/mesoporous structure, the SnO2 spheres exhibited large specific surface areas over 100 m2/g. When 10 vol. % of acetic acid at 200 °C for 20 h was used for the reaction, the obtained SnO2 possessed a higher specific surface area of 145 m2/g (SnO2_10). The gas sensing property of SnO2_10 without an additional noble metal co-catalyst exhibited a large toluene sensing response (Ra/Rg) of 20.2 at 400 °C, which was about 6 times higher and acceptable selectivity compared to those of other samples. The study found that the sensing performance in the SnO2 hierarchical spheres was influenced by several factors e.g. particle morphology, pore size and specific surface area rather than only a single parameter. Therefore, a precise control of those influencing parameters may lead to the optimum sensing property. These findings are important for the further development of the micro-/mesoporous metal-based oxide as an alternative successor for toluene gas sensor material.

元の言語英語
ページ(範囲)15435-15444
ページ数10
ジャーナルCeramics International
45
発行部数12
DOI
出版物ステータス出版済み - 8 15 2019

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Toluene
Chemical sensors
Acetic acid
Specific surface area
Acetic Acid
Pore size
Ethanol
Precious metals
Oxides
Desorption
Gases
Metals
Particle size
Transmission electron microscopy
Adsorption
Fabrication
Scanning electron microscopy
Catalysts

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Process Chemistry and Technology
  • Surfaces, Coatings and Films
  • Materials Chemistry

これを引用

One-step synthesis of micro-/mesoporous SnO2 spheres by solvothermal method for toluene gas sensor. / Hermawan, Angga; Asakura, Yusuke; Inada, Miki; Yin, Shu.

:: Ceramics International, 巻 45, 番号 12, 15.08.2019, p. 15435-15444.

研究成果: ジャーナルへの寄稿記事

Hermawan, Angga ; Asakura, Yusuke ; Inada, Miki ; Yin, Shu. / One-step synthesis of micro-/mesoporous SnO2 spheres by solvothermal method for toluene gas sensor. :: Ceramics International. 2019 ; 巻 45, 番号 12. pp. 15435-15444.
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abstract = "A facile solvothermal synthesis in an ethanol/acetic acid mixture for the fabrication of SnO2 with a controllable hierarchical spherical size and micro-/mesoporosity is presented. SEM, TEM and N2 adsorption/desorption investigation unveiled that the obtained SnO2 spheres exhibited a particle size in the range of 0.6–1.6 μm and a pore size of about 1.4–1.9 nm depending on the volume ratio of acetic acid to ethanol in the reaction mixture, and the spheres were constructed by nanoscale particles. Due to its micro-/mesoporous structure, the SnO2 spheres exhibited large specific surface areas over 100 m2/g. When 10 vol. {\%} of acetic acid at 200 °C for 20 h was used for the reaction, the obtained SnO2 possessed a higher specific surface area of 145 m2/g (SnO2_10). The gas sensing property of SnO2_10 without an additional noble metal co-catalyst exhibited a large toluene sensing response (Ra/Rg) of 20.2 at 400 °C, which was about 6 times higher and acceptable selectivity compared to those of other samples. The study found that the sensing performance in the SnO2 hierarchical spheres was influenced by several factors e.g. particle morphology, pore size and specific surface area rather than only a single parameter. Therefore, a precise control of those influencing parameters may lead to the optimum sensing property. These findings are important for the further development of the micro-/mesoporous metal-based oxide as an alternative successor for toluene gas sensor material.",
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