Optimizing filler network formation in poly(hexahydrotriazine) for realizing high thermal conductivity and low oxygen permeation

Janggeon Lee, Sunbin Hwang, Seoung Ki Lee, Seokhoon Ahn, Se Gyu Jang, Nam Ho You, Chae Bin Kim, Munju Goh

研究成果: Contribution to journalArticle査読

4 被引用数 (Scopus)

抄録

Shape, size, and orientation of fillers within polymer matrix are important factors for realizing various composite functionalities. Here, we describe an industrially scalable approach to preparing composites bearing highly aligned model hexagonal boron nitride filler (hBN) by simple melt-pressing. This outcome is achieved by using a malleable but thermal stiffening polymer matrix. The matrix maintains or even increases its stiffness during processing at elevated temperatures, producing the composites with highly aligned hBN and consequently a high thermal conductivity (28 W/mK). Furthermore, the composite bearing aligned hBN exhibits a 62% reduction in oxygen permeation with only 2.7 vol% of hBN. Since the matrix can be chemically depolymerized with an aid of acid, it is also possible to recover the hBN from the composite without physical/chemical denaturation of the filler, thus the recovered filler can be re-used in the future.

本文言語英語
論文番号121639
ジャーナルpolymer
179
DOI
出版ステータス出版済み - 9 28 2019
外部発表はい

All Science Journal Classification (ASJC) codes

  • 有機化学
  • ポリマーおよびプラスチック
  • 材料化学

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