Organic films containing trinuclear ruthenium clusters that exhibit redox-state-dependent heat-shielding characteristics

Yuki Tomiyasu, Masaaki Abe, Yasushi Morihara, Hiroyuki Ohgi, Tomiaki Otake, Yoshio Hisaeda

    研究成果: Contribution to journalArticle査読

    11 被引用数 (Scopus)

    抄録

    We report here an unprecedented utility of redox-active transition-metal complexes as heat-shielding materials. A poly-(vinyl alcohol) film containing mixed-valent cluster [Ru 3-(μ 3-O)(μ-CH 3CO 2) 6(mbpy +) 3](PF 6) 3 (1) (mbpy + = 1-methyl-4,4′- bipyridinium cation), which strongly absorbs light in the near-infrared region, shows heat-shielding characteristics whose efficiency is found to highly depend on the redox state of the cluster dye.

    本文言語英語
    ページ(範囲)492-493
    ページ数2
    ジャーナルChemistry Letters
    38
    5
    DOI
    出版ステータス出版済み - 7 20 2009

    All Science Journal Classification (ASJC) codes

    • 化学 (全般)

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