Organic synthesis in solid media. Silica gel as an effective and reusable medium for the selective allylation of aldehydes with tetraallyltin

Yong Zhi Jin, Noriyuki Yasuda, Hiroshi Furuno, Junji Inanaga

    研究成果: Contribution to journalArticle査読

    25 被引用数 (Scopus)

    抄録

    Wet silica gel promotes the chemoselective and almost complete allylation of aldehydes with 0.25-0.30 molar equivalents of tetraallyltin without an organic solvent, leaving no organotin compounds, requiring neither extraction nor chromatographic separation after the reaction, and enabling the repeated use of the silica gel.

    本文言語英語
    ページ(範囲)8765-8768
    ページ数4
    ジャーナルTetrahedron Letters
    44
    49
    DOI
    出版ステータス出版済み - 12 1 2003

    All Science Journal Classification (ASJC) codes

    • Biochemistry
    • Drug Discovery
    • Organic Chemistry

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