Organometallic Studies on the Mechanism of Fischer-Tropsch Synthesis

研究成果: ジャーナルへの寄稿記事

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Reductive polymerization of carbon monoxide on heterogeneous catalysts provides hydrocarbons, and is well known as Fischer-Tropsch synthesis. Interest in the mechanism is focused on an initial stage of the reaction, i.e. how to hydrogenate carbon monoxide by metallic species. Two mechanisms have been proposed on the reduction of CO. One involves dissociative cleavage of CO by metals to metal carbide and metal oxide. Another is through stepwise reduction of CO by hydride reduction followed by protonation. Many model reactions have been provided using mononuclear metal complexes or small metal clusters, contributing to an understanding of the mechanism. This article reviews the recent advances.

元の言語英語
ページ(範囲)553-563
ページ数11
ジャーナルJournal of Synthetic Organic Chemistry, Japan
46
発行部数6
DOI
出版物ステータス出版済み - 1 1 1988
外部発表Yes

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All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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