Organoruthenium(ii) and (iii) amidinates, (η5-C5Me5)Ru(η-amidinate) and (η5-C5Me5)RuCl(η-amidinate), as unique redox catalysts for the intramolecular Kharasch reactions: Facile access to a pyrrolizidine alkaloid skeleton under mild conditions

Hideo Nagashima; Mitsuru Gondo; Satoshi Masuda; Hideo Kondo; Yoshitaka Yamaguchi; Kouki Matsubara

doi:10.1039/b209369c

Organoruthenium(ii) and (iii) amidinates, (η⁵-C₅Me₅)Ru(η-amidinate) and (η⁵-C₅Me₅)RuCl(η-amidinate), as unique redox catalysts for the intramolecular Kharasch reactions: Facile access to a pyrrolizidine alkaloid skeleton under mild conditions

Hideo Nagashima, Mitsuru Gondo, Satoshi Masuda, Hideo Kondo, Yoshitaka Yamaguchi, Kouki Matsubara

分子集積化学部門

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

9 被引用数 (Scopus)

抄録

A novel organoruthenium(iii) amidinate, (η⁵-C₅Me₅)RuCl(η-ⁱPrN=C(Me)NⁱPr) (2), has been prepared by oxidation of organoruthenium amidinate, (η⁵-C₅Me₅)Ru(η-ⁱPrN=C(Me)NⁱPr) (1), by organic chlorides; both 1 and 2 are found to be good catalysts for atom-transfer cyclization of N-allyltrichloroacetamides which are useful for successful preparation of a pyrrolizidine alkaloid skeleton under mild conditions.

本文言語	英語
ページ（範囲）	442-443
ページ数	2
ジャーナル	Chemical Communications
巻	3
号	3
DOI	https://doi.org/10.1039/b209369c
出版ステータス	出版済み - 1月 1 2003

!!!All Science Journal Classification (ASJC) codes

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学 (全般)
表面、皮膜および薄膜
金属および合金
材料化学

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10.1039/b209369c

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フィンガープリント

「Organoruthenium(ii) and (iii) amidinates, (η⁵-C₅Me₅)Ru(η-amidinate) and (η⁵-C₅Me₅)RuCl(η-amidinate), as unique redox catalysts for the intramolecular Kharasch reactions: Facile access to a pyrrolizidine alkaloid skeleton under mild conditions」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

Nagashima, H., Gondo, M., Masuda, S., Kondo, H., Yamaguchi, Y., & Matsubara, K. (2003). Organoruthenium(ii) and (iii) amidinates, (η⁵-C₅Me₅)Ru(η-amidinate) and (η⁵-C₅Me₅)RuCl(η-amidinate), as unique redox catalysts for the intramolecular Kharasch reactions: Facile access to a pyrrolizidine alkaloid skeleton under mild conditions. Chemical Communications, 3(3), 442-443. https://doi.org/10.1039/b209369c

Organoruthenium(ii) and (iii) amidinates, (η⁵-C₅Me₅)Ru(η-amidinate) and (η⁵-C₅Me₅)RuCl(η-amidinate), as unique redox catalysts for the intramolecular Kharasch reactions: Facile access to a pyrrolizidine alkaloid skeleton under mild conditions. / Nagashima, Hideo; Gondo, Mitsuru; Masuda, Satoshi その他.
In: Chemical Communications, Vol. 3, No. 3, 01.01.2003, p. 442-443.

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

Nagashima, H, Gondo, M, Masuda, S, Kondo, H, Yamaguchi, Y & Matsubara, K 2003, 'Organoruthenium(ii) and (iii) amidinates, (η⁵-C₅Me₅)Ru(η-amidinate) and (η⁵-C₅Me₅)RuCl(η-amidinate), as unique redox catalysts for the intramolecular Kharasch reactions: Facile access to a pyrrolizidine alkaloid skeleton under mild conditions', Chemical Communications, vol. 3, no. 3, pp. 442-443. https://doi.org/10.1039/b209369c

Nagashima H, Gondo M, Masuda S, Kondo H, Yamaguchi Y, Matsubara K. Organoruthenium(ii) and (iii) amidinates, (η⁵-C₅Me₅)Ru(η-amidinate) and (η⁵-C₅Me₅)RuCl(η-amidinate), as unique redox catalysts for the intramolecular Kharasch reactions: Facile access to a pyrrolizidine alkaloid skeleton under mild conditions. Chemical Communications. 2003 1月 1;3(3):442-443. doi: 10.1039/b209369c

Nagashima, Hideo ; Gondo, Mitsuru ; Masuda, Satoshi その他. / Organoruthenium(ii) and (iii) amidinates, (η⁵-C₅Me₅)Ru(η-amidinate) and (η⁵-C₅Me₅)RuCl(η-amidinate), as unique redox catalysts for the intramolecular Kharasch reactions : Facile access to a pyrrolizidine alkaloid skeleton under mild conditions. In: Chemical Communications. 2003 ; Vol. 3, No. 3. pp. 442-443.

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