Ortho-vinylation reaction of phenols with ethyne

Masahiko Yamaguchi, Mieko Arisawa, Kenji Omata, Kuninobu Kabuto, Masahiro Hirama, Tadafumi Uchimaru

研究成果: Contribution to journalArticle査読

32 被引用数 (Scopus)

抄録

Phenols were vinylated at the ortho-position with ethyne in the presence of SnCl4-Bu3N reagent. The reaction was applicable to phenols possessing either electron-donating or electron-withdrawing groups. 2,6-Divinylphenols were synthesized under modified conditions. A reaction mechanism involving carbostannylation of alkynyltin and phenoxytin was discussed.

本文言語英語
ページ(範囲)7298-7305
ページ数8
ジャーナルJournal of Organic Chemistry
63
21
DOI
出版ステータス出版済み - 10 16 1998
外部発表はい

All Science Journal Classification (ASJC) codes

  • 有機化学

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