Orthogonal growth of horizontally aligned single-walled carbon nanotube arrays

Hiroki Ago, Tetsushi Nishi, Kenta Imamoto, Naoki Ishigami, Masaharu Tsuji, Tatsuya Ikuta, Koji Takahashi

研究成果: Contribution to journalArticle査読

15 被引用数 (Scopus)


Direction-controlled growth of horizontally aligned single-walled carbon nanotubes (SWNTs) on r-plane sapphire substrates and their alignment mechanisms are demonstrated. On a flat r-plane substrate, anisotropic nanotube-substrate interaction is known to align SWNTs parallel to the [11̄01̄] direction of the sapphire. We find that the introduction of a slight miscut (-1° inclined to the [11̄01̄] direction) on the substrate changed the SWNT growth direction by 90°, aligning perpendicular to the [11̄01̄] direction. This dramatic change of the growth direction is explained by the contribution of newly proposed one-dimensional surface atomic rows and/or atomic steps appeared on the r-plane. Annealing the substrate in hydrogen atmosphere prior to SWNT growth recovers the original nanotube growth direction, while annealing in air deteriorates the alignment. The direct growth of an orthogonally aligned SWNT array is achieved through optimized surface treatment. Site-selective directional control of aligned SWNTs is also demonstrated by applying hydrogen annealing to the miscut substrate whose surface is partially covered with SiO2. Our study gives insights into the alignment mechanism on single crystal substrates and offers a new means to assemble SWNTs for advanced integrated structures.

ジャーナルJournal of Physical Chemistry C
出版ステータス出版済み - 8 5 2010

All Science Journal Classification (ASJC) codes

  • 電子材料、光学材料、および磁性材料
  • エネルギー(全般)
  • 物理化学および理論化学
  • 表面、皮膜および薄膜


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