Oxide-supported palladium and gold nanoparticles for catalytic C-H transformations

Tamao Ishida, Zhenzhong Zhang, Haruno Murayama, Makoto Tokunaga

研究成果: Contribution to journalArticle査読

4 被引用数 (Scopus)

抄録

C-H transformations catalyzed by heterogeneous Pd and Au catalysts are disclosed. For palladium, Pd(0), PdO, and Pd(OH) 2 worked as catalytically active species involved in oxidative addition, electrophilic substitution, and concerted metalation deprotonation pathways depending on the reaction under investigation. We also found that Au(0) nanoparticles catalyzed C-H coupling and discuss the difference in catalytic properties between Pd and Au. The role of metal oxide (MO x) supports is also mentioned: MO x not only stabilizes Pd and Au particles but also creates cationic metal sites at the perimeter interface, and these play an important role in activating the substrates.

本文言語英語
ページ(範囲)1150-1161
ページ数12
ジャーナルYuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
75
11
DOI
出版ステータス出版済み - 2017

All Science Journal Classification (ASJC) codes

  • 有機化学

フィンガープリント

「Oxide-supported palladium and gold nanoparticles for catalytic C-H transformations」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル