Oxygen permeation properties of partially A-site substituted BaFe O3-δ perovskites

Tetsuya Kida, Daisuke Takauchi, Ken Watanabe, Masayoshi Yuasa, Kengo Shimanoe, Yasutake Teraoka, Noboru Yamazoe

研究成果: Contribution to journalArticle査読

67 被引用数 (Scopus)

抄録

To explore oxygen permeable materials, oxygen permeation properties of partially A-site substituted BaFe O3-δ perovskites were investigated. Ba sites in BaFe O3-δ were substituted with cations such as Na, Rb, Ca, Y, and La by 5%. The partial substitution with Ca, Y, and La, whose ionic radii are smaller than that of Ba, succeeded in stabilizing a cubic perovskite structure that is a highly oxygen permeable phase, as revealed by X-ray diffraction analysis. This can be explained in terms of a decrease in the tolerance factor (t). Among the Ba0.95 M 0.05 Fe O3-δ (M = Na, Rb, Ca, Y, and La) membranes tested, Ba0.95 La0.05 Fe O3-δ showed the highest oxygen permeability at 600-930°C, owing to the stabilization of the cubic phase without the formation of impurity phases. From chemical analysis, the oxygen permeability of Ba1-x Lax Fe O 3-δ membranes was correlated with the amount of oxygen defects (δ) in the lattice. The oxygen permeation flux of Ba0.95 La0.05 Fe O3-δ membrane was significantly increased by reducing its thickness. Furthermore, a Ba0.975 La0.025 Fe O3-δ membrane exhibited good phase stability under He flow at elevated temperatures. The obtained results indicate the promising properties of Ba1-x Lax Fe O3-δ membranes as a cobalt-free material that has a high oxygen permeability, good phase stability, and low cost.

本文言語英語
ジャーナルJournal of the Electrochemical Society
156
12
DOI
出版ステータス出版済み - 11 10 2009

All Science Journal Classification (ASJC) codes

  • 電子材料、光学材料、および磁性材料
  • 再生可能エネルギー、持続可能性、環境
  • 表面、皮膜および薄膜
  • 電気化学
  • 材料化学

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