Oxygen pumping based on c-axis-oriented lanthanum silicate ceramics: Challenge toward low operating temperature

Ken Watanabe, Shingo Ide, Takashi Kumagai, Takaaki Fujino, Koichi Suematsu, Kengo Shimanoe

研究成果: Contribution to journalArticle査読

5 被引用数 (Scopus)

抄録

A new electrochemical oxygen separation pump was developed by using c-axis-oriented La 9.66 Si 5.3 B 0.7 O 26.14 (c-LSBO), which has high oxide-ionic conductivity (>10 13 S cm 11 ) up to 300°C. Interfacial resistance between the electrode and c-LSBO was investigated to realize the full potential of LSBO as an oxygen separation material. The formation of a Sm-doped CeO 2 (SDC) thin film (thickness: 300 nm) between the electrode and c-LSBO was effective for suppressing the interfacial resistance. Furthermore, a mixed conductive La 0.6 Sr 0.4 Co 0.78 Ni 0.02 Fe 0.2 O 3 1 ¤ (LSCFN) was applied to the electrode for enhancing the oxygen reduction/evolution activity on the electrode. The LSCFN/SDC/c-LSBO symmetric cell showed an oxygen permeation flux of 3.5 mL cm 12 min 11 (1.0 A cm 12 ) at 600°C under an applied DC voltage of 1.5 V; this value was 67 times that of Pt/c-LSBO. This oxygen pump based on the LSCFN/SDC/c-LSBO symmetric cell would find promising application in oxygen separation at intermediate temperatures. Further reduction of the interfacial resistance and polarization resistance of the electrode may decrease the operating temperatures to below 400°C.

本文言語英語
ページ(範囲)1-4
ページ数4
ジャーナルJournal of the Ceramic Society of Japan
DOI
出版ステータス出版済み - 1 2019

All Science Journal Classification (ASJC) codes

  • セラミックおよび複合材料
  • 化学 (全般)
  • 凝縮系物理学
  • 材料化学

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