PAEs with heteroaromatic rings

Takakazu Yamamoto, Isao Yamaguchi, Takuma Yasuda

研究成果: Contribution to journalReview article査読

23 被引用数 (Scopus)

抄録

This article reviews the synthesis and chemical properties of poly(aryleneethynylene)s, PAEs, consisting of sulfur-containing heteroaromatic rings (e.g., thiophene), nitrogen-containing heteroaromatic rings (e.g., pyridine), and silicon-containing heteroaromatic rings (e.g., silole). The polymers are usually prepared via Pd-catalyzed C-C coupling between diethynyl compounds and dihalo organic compounds. However, synthesis using other monomers such as distannylacetylenic compounds is also possible. This article describes the chemical and optical properties of PAEs, which are affected by the basic electronic properties of the heteroaromatic ring and the molecular structure of the PAE.

本文言語英語
ページ(範囲)181-208
ページ数28
ジャーナルAdvances in Polymer Science
177
DOI
出版ステータス出版済み - 2005
外部発表はい

All Science Journal Classification (ASJC) codes

  • 化学工学(全般)
  • 有機化学
  • ポリマーおよびプラスチック

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