Palladium-catalyzed addition reaction of olefins, carbon tetrachloride and carbon monoxide in alcohols to give 2-alkyl-4,4,4-trichlorobutanoates

Jiro Tsuji; Koji Sato; Hideo Nagashima

doi:10.1016/S0040-4020(01)96745-6

Palladium-catalyzed addition reaction of olefins, carbon tetrachloride and carbon monoxide in alcohols to give 2-alkyl-4,4,4-trichlorobutanoates

Jiro Tsuji, Koji Sato, Hideo Nagashima

研究成果: Contribution to journal › Article › 査読

18 被引用数 (Scopus)

抄録

Pd(OAc)₂ combined with PPh₃ is a good catalyst for the addition reaction of CCl₄ and CO to olefins in ethanol to afford ethyl 2-alkyl-4,4,4-trichlorobutanoates. The esters were obtained in satisfactory yields when the reaction was carried out at 50° in the presence of K₂CO₃ under CO pressure.

本文言語	英語
ページ（範囲）	5003-5006
ページ数	4
ジャーナル	Tetrahedron
巻	41
号	21
DOI	https://doi.org/10.1016/S0040-4020(01)96745-6
出版ステータス	出版済み - 1985
外部発表	はい

All Science Journal Classification (ASJC) codes

生化学
創薬
有機化学

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10.1016/S0040-4020(01)96745-6

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引用スタイル

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abstract = "Pd(OAc)2 combined with PPh3 is a good catalyst for the addition reaction of CCl4 and CO to olefins in ethanol to afford ethyl 2-alkyl-4,4,4-trichlorobutanoates. The esters were obtained in satisfactory yields when the reaction was carried out at 50° in the presence of K2CO3 under CO pressure.",

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T1 - Palladium-catalyzed addition reaction of olefins, carbon tetrachloride and carbon monoxide in alcohols to give 2-alkyl-4,4,4-trichlorobutanoates

AU - Tsuji, Jiro

AU - Sato, Koji

AU - Nagashima, Hideo

PY - 1985

Y1 - 1985

N2 - Pd(OAc)2 combined with PPh3 is a good catalyst for the addition reaction of CCl4 and CO to olefins in ethanol to afford ethyl 2-alkyl-4,4,4-trichlorobutanoates. The esters were obtained in satisfactory yields when the reaction was carried out at 50° in the presence of K2CO3 under CO pressure.

AB - Pd(OAc)2 combined with PPh3 is a good catalyst for the addition reaction of CCl4 and CO to olefins in ethanol to afford ethyl 2-alkyl-4,4,4-trichlorobutanoates. The esters were obtained in satisfactory yields when the reaction was carried out at 50° in the presence of K2CO3 under CO pressure.

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