Palladium-catalyzed addition reaction of polyhaloalkanes to olefins

Jiro Tsuji; Koji Sato; Hideo Nagashima

doi:10.1016/S0040-4020(01)96431-2

Palladium-catalyzed addition reaction of polyhaloalkanes to olefins

Jiro Tsuji, Koji Sato, Hideo Nagashima

研究成果: Contribution to journal › Article › 査読

40 被引用数 (Scopus)

抄録

Pd(OAc)₂ combined with phosphines catalyzes homolytic cleavage of the C-Cl bond of CCl₄ and CCl₃CO₂CH₃ leading to facile addition to olefins under mild conditions. BrCCl₃ also reacts with olefins to give 1,1,1-trichloro-3-bromoalkanes. The reaction is accelerated under CO atmosphere, and the presence of bases such as NaOAc or K₂CO₃ is essential to attain high yields of the adducts.

本文言語	英語
ページ（範囲）	393-397
ページ数	5
ジャーナル	Tetrahedron
巻	41
号	2
DOI	https://doi.org/10.1016/S0040-4020(01)96431-2
出版ステータス	出版済み - 1 1 1985
外部発表	はい

All Science Journal Classification (ASJC) codes

生化学
創薬
有機化学

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10.1016/S0040-4020(01)96431-2

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title = "Palladium-catalyzed addition reaction of polyhaloalkanes to olefins",

abstract = "Pd(OAc)2 combined with phosphines catalyzes homolytic cleavage of the C-Cl bond of CCl4 and CCl3CO2CH3 leading to facile addition to olefins under mild conditions. BrCCl3 also reacts with olefins to give 1,1,1-trichloro-3-bromoalkanes. The reaction is accelerated under CO atmosphere, and the presence of bases such as NaOAc or K2CO3 is essential to attain high yields of the adducts.",

author = "Jiro Tsuji and Koji Sato and Hideo Nagashima",

year = "1985",

month = jan,

day = "1",

doi = "10.1016/S0040-4020(01)96431-2",

language = "English",

volume = "41",

pages = "393--397",

journal = "Tetrahedron",

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T1 - Palladium-catalyzed addition reaction of polyhaloalkanes to olefins

AU - Tsuji, Jiro

AU - Sato, Koji

AU - Nagashima, Hideo

PY - 1985/1/1

Y1 - 1985/1/1

N2 - Pd(OAc)2 combined with phosphines catalyzes homolytic cleavage of the C-Cl bond of CCl4 and CCl3CO2CH3 leading to facile addition to olefins under mild conditions. BrCCl3 also reacts with olefins to give 1,1,1-trichloro-3-bromoalkanes. The reaction is accelerated under CO atmosphere, and the presence of bases such as NaOAc or K2CO3 is essential to attain high yields of the adducts.

AB - Pd(OAc)2 combined with phosphines catalyzes homolytic cleavage of the C-Cl bond of CCl4 and CCl3CO2CH3 leading to facile addition to olefins under mild conditions. BrCCl3 also reacts with olefins to give 1,1,1-trichloro-3-bromoalkanes. The reaction is accelerated under CO atmosphere, and the presence of bases such as NaOAc or K2CO3 is essential to attain high yields of the adducts.

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U2 - 10.1016/S0040-4020(01)96431-2

DO - 10.1016/S0040-4020(01)96431-2

M3 - Article

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VL - 41

SP - 393

EP - 397

JO - Tetrahedron

JF - Tetrahedron

SN - 0040-4020

IS - 2

ER -

Palladium-catalyzed addition reaction of polyhaloalkanes to olefins

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