抄録
Pd(OAc)2 combined with phosphines catalyzes homolytic cleavage of the C-Cl bond of CCl4 and CCl3CO2CH3 leading to facile addition to olefins under mild conditions. BrCCl3 also reacts with olefins to give 1,1,1-trichloro-3-bromoalkanes. The reaction is accelerated under CO atmosphere, and the presence of bases such as NaOAc or K2CO3 is essential to attain high yields of the adducts.
本文言語 | 英語 |
---|---|
ページ(範囲) | 393-397 |
ページ数 | 5 |
ジャーナル | Tetrahedron |
巻 | 41 |
号 | 2 |
DOI | |
出版ステータス | 出版済み - 1月 1 1985 |
外部発表 | はい |
!!!All Science Journal Classification (ASJC) codes
- 生化学
- 創薬
- 有機化学