Palladium-catalyzed benzylation of active methine compounds without additional base: Remarkable effect of 1,5-cyclooctadiene

Ryoichi Kuwano, Yutaka Kondo

研究成果: Contribution to journalArticle査読

58 被引用数 (Scopus)

抄録

(Chemical Equation Presented) The palladium complex prepared from DPPF and Cp(η3-C3H5)Pd is an effective catalyst for the alkylation of active methine compounds with benzylic carbonates under neutral conditions. The addition of 1,5-cyclooctadiene brought about remarkable improvement in the lifetime of the palladium catalyst, which led to high yields of the desired benzylation products.

本文言語英語
ページ(範囲)3545-3547
ページ数3
ジャーナルOrganic letters
6
20
DOI
出版ステータス出版済み - 9 30 2004

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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