Palladium-Catalyzed Decarboxylation of Benzyl Fluorobenzoates

Yusuke Makida, Yasutaka Matsumoto, Ryoichi Kuwano

研究成果: Contribution to journalArticle

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抜粋

The decarboxylation of benzyl fluorobenzoates has been developed by using the palladium catalyst prepared in situ from Pd(η 3 -allyl)Cp and bulky monophosphine ligand XPhos. The catalytic reaction afforded a range of fluorinated diarylmethanes in good yields with broad functional-group compatibility. The substrates were readily synthesized by condensation of the corresponding benzoic acid with benzyl alcohol. Therefore, the transformation is formally regarded as a cross-coupling reaction between fluorine-containing benzoic acids and benzyl alcohols.

元の言語英語
ページ(範囲)2573-2576
ページ数4
ジャーナルSynlett
28
発行部数19
DOI
出版物ステータス出版済み - 12 1 2017

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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