Palladium-catalyzed formal [4+2] cycloaddtion of o-xylylenes with olefins

Ryoichi Kuwano; Takenori Shige

doi:10.1021/ja070012l

Palladium-catalyzed formal [4+2] cycloaddtion of o-xylylenes with olefins

Ryoichi Kuwano, Takenori Shige

複合領域化学

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

34 被引用数 (Scopus)

抄録

o-(Silylmethyl)benzylic carbonates reacted with various conjugated olefins in the presence of the palladium catalyst, which was generated in situ from Pd(η³-C₃H₅)Cp and 1,2-bis(diphenylphosphino)ethane (DPPE). The reaction provided 2- and/or 3-substituted tetralins in good yield. The catalytic reaction described here is equivalent to the [4+2] cycloaddition of o-xylylenes with dienophiles.

本文言語	英語
ページ（範囲）	3802-3803
ページ数	2
ジャーナル	Journal of the American Chemical Society
巻	129
号	13
DOI	https://doi.org/10.1021/ja070012l
出版ステータス	出版済み - 4月 4 2007

!!!All Science Journal Classification (ASJC) codes

触媒
化学 (全般)
生化学
コロイド化学および表面化学

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10.1021/ja070012l

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title = "Palladium-catalyzed formal [4+2] cycloaddtion of o-xylylenes with olefins",

abstract = "o-(Silylmethyl)benzylic carbonates reacted with various conjugated olefins in the presence of the palladium catalyst, which was generated in situ from Pd(η3-C3H5)Cp and 1,2-bis(diphenylphosphino)ethane (DPPE). The reaction provided 2- and/or 3-substituted tetralins in good yield. The catalytic reaction described here is equivalent to the [4+2] cycloaddition of o-xylylenes with dienophiles.",

author = "Ryoichi Kuwano and Takenori Shige",

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day = "4",

doi = "10.1021/ja070012l",

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AU - Kuwano, Ryoichi

AU - Shige, Takenori

PY - 2007/4/4

Y1 - 2007/4/4

N2 - o-(Silylmethyl)benzylic carbonates reacted with various conjugated olefins in the presence of the palladium catalyst, which was generated in situ from Pd(η3-C3H5)Cp and 1,2-bis(diphenylphosphino)ethane (DPPE). The reaction provided 2- and/or 3-substituted tetralins in good yield. The catalytic reaction described here is equivalent to the [4+2] cycloaddition of o-xylylenes with dienophiles.

AB - o-(Silylmethyl)benzylic carbonates reacted with various conjugated olefins in the presence of the palladium catalyst, which was generated in situ from Pd(η3-C3H5)Cp and 1,2-bis(diphenylphosphino)ethane (DPPE). The reaction provided 2- and/or 3-substituted tetralins in good yield. The catalytic reaction described here is equivalent to the [4+2] cycloaddition of o-xylylenes with dienophiles.

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JF - Journal of the American Chemical Society

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Palladium-catalyzed formal [4+2] cycloaddtion of o-xylylenes with olefins

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!!!All Science Journal Classification (ASJC) codes

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