Palladium-catalyzed formal [4+2] cycloaddtion of o-xylylenes with olefins

Ryoichi Kuwano, Takenori Shige

研究成果: ジャーナルへの寄稿記事

29 引用 (Scopus)

抄録

o-(Silylmethyl)benzylic carbonates reacted with various conjugated olefins in the presence of the palladium catalyst, which was generated in situ from Pd(η3-C3H5)Cp and 1,2-bis(diphenylphosphino)ethane (DPPE). The reaction provided 2- and/or 3-substituted tetralins in good yield. The catalytic reaction described here is equivalent to the [4+2] cycloaddition of o-xylylenes with dienophiles.

元の言語英語
ページ(範囲)3802-3803
ページ数2
ジャーナルJournal of the American Chemical Society
129
発行部数13
DOI
出版物ステータス出版済み - 4 4 2007

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Tetrahydronaphthalenes
Cycloaddition
Carbonates
Cycloaddition Reaction
Palladium
Alkenes
Ethane
Olefins
Catalysts
bis(diphenylphosphine)ethane

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

これを引用

Palladium-catalyzed formal [4+2] cycloaddtion of o-xylylenes with olefins. / Kuwano, Ryoichi; Shige, Takenori.

:: Journal of the American Chemical Society, 巻 129, 番号 13, 04.04.2007, p. 3802-3803.

研究成果: ジャーナルへの寄稿記事

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