Palladium-catalyzed nucleophilic substitution of diarylmethyl carbonates with malonate carbanions

Ryoichi Kuwano, Hiroki Kusano

研究成果: ジャーナルへの寄稿記事

20 引用 (Scopus)

抄録

The nucleophilic substitution of diarylmethyl carbonates with malonate carbanions proceeded in the presence of [Pd(π-C3H 5)(cod)]BF4-Cy-Xantphos, giving the desired (diarylmethyl)malonates in up to 90% yield. The yield was extremely affected by choice of the phosphine ligand.

元の言語英語
ページ(範囲)528-529
ページ数2
ジャーナルChemistry Letters
36
発行部数4
DOI
出版物ステータス出版済み - 4 5 2007

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phosphine
Malonates
Carbonates
Palladium
Substitution reactions
Ligands
xantphos
malonic acid

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

これを引用

Palladium-catalyzed nucleophilic substitution of diarylmethyl carbonates with malonate carbanions. / Kuwano, Ryoichi; Kusano, Hiroki.

:: Chemistry Letters, 巻 36, 番号 4, 05.04.2007, p. 528-529.

研究成果: ジャーナルへの寄稿記事

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abstract = "The nucleophilic substitution of diarylmethyl carbonates with malonate carbanions proceeded in the presence of [Pd(π-C3H 5)(cod)]BF4-Cy-Xantphos, giving the desired (diarylmethyl)malonates in up to 90{\%} yield. The yield was extremely affected by choice of the phosphine ligand.",
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