Palladium-catalyzed nucleophilic substitution of diarylmethyl carbonates with malonate carbanions

Ryoichi Kuwano; Hiroki Kusano

doi:10.1246/cl.2007.528

Palladium-catalyzed nucleophilic substitution of diarylmethyl carbonates with malonate carbanions

Ryoichi Kuwano, Hiroki Kusano

複合領域化学

研究成果: Contribution to journal › Article › 査読

23 被引用数 (Scopus)

抄録

The nucleophilic substitution of diarylmethyl carbonates with malonate carbanions proceeded in the presence of [Pd(π-C₃H ₅)(cod)]BF₄-Cy-Xantphos, giving the desired (diarylmethyl)malonates in up to 90% yield. The yield was extremely affected by choice of the phosphine ligand.

本文言語	英語
ページ（範囲）	528-529
ページ数	2
ジャーナル	Chemistry Letters
巻	36
号	4
DOI	https://doi.org/10.1246/cl.2007.528
出版ステータス	出版済み - 4 5 2007

All Science Journal Classification (ASJC) codes

Chemistry(all)

文献へのアクセス

10.1246/cl.2007.528

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引用スタイル

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title = "Palladium-catalyzed nucleophilic substitution of diarylmethyl carbonates with malonate carbanions",

abstract = "The nucleophilic substitution of diarylmethyl carbonates with malonate carbanions proceeded in the presence of [Pd(π-C3H 5)(cod)]BF4-Cy-Xantphos, giving the desired (diarylmethyl)malonates in up to 90% yield. The yield was extremely affected by choice of the phosphine ligand.",

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AB - The nucleophilic substitution of diarylmethyl carbonates with malonate carbanions proceeded in the presence of [Pd(π-C3H 5)(cod)]BF4-Cy-Xantphos, giving the desired (diarylmethyl)malonates in up to 90% yield. The yield was extremely affected by choice of the phosphine ligand.

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