Palladium-catalyzed oxidation of cyclohexanones to conjugated enones using molecular oxygen

Makoto Tokunaga, Saki Harada, Tetsuo Iwasawa, Yasushi Obora, Yasushi Tsuji

研究成果: ジャーナルへの寄稿記事

34 引用 (Scopus)

抄録

Oxidation of cyclohexanones into conjugated enones with molecular oxygen as oxidant was achieved by palladium catalysts. A catalyst system consists of 1 mol % Pd(OCOCF3)2 and 5,5′-dimethyl-2,2′-bipyridine accomplished maximum 84% yield for the oxidation of cyclohexanone and 51-78% yields for 4-substituted-cyclohexanones.

元の言語英語
ページ(範囲)6860-6862
ページ数3
ジャーナルTetrahedron Letters
48
発行部数39
DOI
出版物ステータス出版済み - 9 24 2007
外部発表Yes

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Cyclohexanones
Molecular oxygen
Palladium
Oxygen
Oxidation
Catalysts
Oxidants

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

これを引用

Palladium-catalyzed oxidation of cyclohexanones to conjugated enones using molecular oxygen. / Tokunaga, Makoto; Harada, Saki; Iwasawa, Tetsuo; Obora, Yasushi; Tsuji, Yasushi.

:: Tetrahedron Letters, 巻 48, 番号 39, 24.09.2007, p. 6860-6862.

研究成果: ジャーナルへの寄稿記事

Tokunaga, Makoto ; Harada, Saki ; Iwasawa, Tetsuo ; Obora, Yasushi ; Tsuji, Yasushi. / Palladium-catalyzed oxidation of cyclohexanones to conjugated enones using molecular oxygen. :: Tetrahedron Letters. 2007 ; 巻 48, 番号 39. pp. 6860-6862.
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