Palladium-catalyzed synthesis of dibenzophosphole oxides via intramolecular dehydrogenative cyclization

Yoichiro Kuninobu; Takuya Yoshida; Kazuhiko Takai

doi:10.1021/jo201030j

Palladium-catalyzed synthesis of dibenzophosphole oxides via intramolecular dehydrogenative cyclization

Yoichiro Kuninobu, Takuya Yoshida, Kazuhiko Takai

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

126 被引用数 (Scopus)

抄録

Dibenzophosphole oxides were obtained from secondary hydrophosphine oxides with a biphenyl group by dehydrogenation via phosphine-hydrogen and carbon-hydrogen bond cleavage in the presence of a catalytic amount of palladium(II) acetate, Pd(OAc)₂. By using this reaction, a ladder-type dibenzophosphole oxide could also be synthesized by double intramolecular dehydrogenative cyclization.

本文言語	英語
ページ（範囲）	7370-7376
ページ数	7
ジャーナル	Journal of Organic Chemistry
巻	76
号	18
DOI	https://doi.org/10.1021/jo201030j
出版ステータス	出版済み - 9月 16 2011
外部発表	はい

!!!All Science Journal Classification (ASJC) codes

有機化学

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10.1021/jo201030j

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abstract = "Dibenzophosphole oxides were obtained from secondary hydrophosphine oxides with a biphenyl group by dehydrogenation via phosphine-hydrogen and carbon-hydrogen bond cleavage in the presence of a catalytic amount of palladium(II) acetate, Pd(OAc)2. By using this reaction, a ladder-type dibenzophosphole oxide could also be synthesized by double intramolecular dehydrogenative cyclization.",

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AU - Kuninobu, Yoichiro

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AU - Takai, Kazuhiko

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N2 - Dibenzophosphole oxides were obtained from secondary hydrophosphine oxides with a biphenyl group by dehydrogenation via phosphine-hydrogen and carbon-hydrogen bond cleavage in the presence of a catalytic amount of palladium(II) acetate, Pd(OAc)2. By using this reaction, a ladder-type dibenzophosphole oxide could also be synthesized by double intramolecular dehydrogenative cyclization.

AB - Dibenzophosphole oxides were obtained from secondary hydrophosphine oxides with a biphenyl group by dehydrogenation via phosphine-hydrogen and carbon-hydrogen bond cleavage in the presence of a catalytic amount of palladium(II) acetate, Pd(OAc)2. By using this reaction, a ladder-type dibenzophosphole oxide could also be synthesized by double intramolecular dehydrogenative cyclization.

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Palladium-catalyzed synthesis of dibenzophosphole oxides via intramolecular dehydrogenative cyclization

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!!!All Science Journal Classification (ASJC) codes

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