Palladium complex catalyzed acylation of allylic esters with acylstannanes: Complementary method to the acylation with acylsilanes

Yasushi Obora, Masafumi Nakanishi, Makoto Tokunaga, Yasushi Tsuji

研究成果: Contribution to journalArticle査読

40 被引用数 (Scopus)

抄録

Palladium-catalyzed acylation of allylic trifluoroacetates (2) using acylstannanes (1) is reported. The reaction serves as a complementary method to the previously reported acylation with acylsilane (4). In particular, the reaction is profitable in the acylation of unsubstituted allyl trifluoroacetate (2a) and benzoylation of allylic trifluoroacetates to afford synthetically useful β,γ-unsaturated ketones (3) in good yields without undesirable isomerizations.

本文言語英語
ページ(範囲)5835-5837
ページ数3
ジャーナルJournal of Organic Chemistry
67
16
DOI
出版ステータス出版済み - 8 9 2002
外部発表はい

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

フィンガープリント 「Palladium complex catalyzed acylation of allylic esters with acylstannanes: Complementary method to the acylation with acylsilanes」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル