Pathway of the Formation of 2-Methyltetrahydrofuran from Pentane in Vapor-phase Oxidation

Hideo Nagata, Yoshihiro Takiyama, Masahiro Kishida, Katsuhiko Wakabayashi, Norihiro Yamamoto

研究成果: ジャーナルへの寄稿記事

抄録

The homogeneous oxidation of pentane was investigated in vapor phase. Main products were 2-methyl-tetrahydrofuran (2-MTHF) and pentenes at comparably low temperatures, besides ethylene and propylene from decomposition of pentane at higher temperatures. The yield of 2-MTHF rapidly increased with increase in residence time, and the yield of pentenes reached maximum at a residence time of about 35 s. The distribution of products from pentane was similar to that from 1-pentene. It is presumed from these results that 2-MTHF might be formed through the addition of oxygen to 2-pentyl radical or 1-pentyl radical produced from pentane at shorter residence times. Further, it might be formed predominantly through the addition of oxygen to 1-pentene produced from pentane at longer residence times.

元の言語英語
ページ(範囲)203-207
ページ数5
ジャーナルjournal of the japan petroleum institute
38
発行部数3
DOI
出版物ステータス出版済み - 1 1 1995

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Vapors
Oxidation
Oxygen
Propylene
Ethylene
Decomposition
Temperature

All Science Journal Classification (ASJC) codes

  • Fuel Technology
  • Energy Engineering and Power Technology

これを引用

Pathway of the Formation of 2-Methyltetrahydrofuran from Pentane in Vapor-phase Oxidation. / Nagata, Hideo; Takiyama, Yoshihiro; Kishida, Masahiro; Wakabayashi, Katsuhiko; Yamamoto, Norihiro.

:: journal of the japan petroleum institute, 巻 38, 番号 3, 01.01.1995, p. 203-207.

研究成果: ジャーナルへの寄稿記事

Nagata, Hideo ; Takiyama, Yoshihiro ; Kishida, Masahiro ; Wakabayashi, Katsuhiko ; Yamamoto, Norihiro. / Pathway of the Formation of 2-Methyltetrahydrofuran from Pentane in Vapor-phase Oxidation. :: journal of the japan petroleum institute. 1995 ; 巻 38, 番号 3. pp. 203-207.
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AU - Yamamoto, Norihiro

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