Pathway of the Formation of 2-Methyltetrahydrofuran from Pentane in Vapor-phase Oxidation

Hideo Nagata, Yoshihiro Takiyama, Masahiro Kishida, Katsuhiko Wakabayashi, Norihiro Yamamoto

研究成果: Contribution to journalArticle査読

抄録

The homogeneous oxidation of pentane was investigated in vapor phase. Main products were 2-methyl-tetrahydrofuran (2-MTHF) and pentenes at comparably low temperatures, besides ethylene and propylene from decomposition of pentane at higher temperatures. The yield of 2-MTHF rapidly increased with increase in residence time, and the yield of pentenes reached maximum at a residence time of about 35 s. The distribution of products from pentane was similar to that from 1-pentene. It is presumed from these results that 2-MTHF might be formed through the addition of oxygen to 2-pentyl radical or 1-pentyl radical produced from pentane at shorter residence times. Further, it might be formed predominantly through the addition of oxygen to 1-pentene produced from pentane at longer residence times.

本文言語英語
ページ(範囲)203-207
ページ数5
ジャーナルjournal of the japan petroleum institute
38
3
DOI
出版ステータス出版済み - 1995

All Science Journal Classification (ASJC) codes

  • Fuel Technology
  • Energy Engineering and Power Technology

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