Perfluorinated meso-aryl-substituted expanded porphyrins

Soji Shimizu, Ji Young Shin, Hiroyuki Furuta, Rami Ismael, Atsuhiro Osuka

研究成果: Contribution to journalArticle査読

66 被引用数 (Scopus)

抄録

Twisted figure-of-eight structures are found for the perfluorinated meso-aryl-substituted expanded porphyrins synthesized from 3,4-difluoropyrrole and pentafluorobenzaldehyde under modified Rothemund-Lindsey conditions. The crystal structure of the [26]hexaphyrin (see picture) consists of two almost planar tripyrrolic subunits which are tilted by approximately 60° in which a distinct alternation in the bond lengths of the π-electronic system is evident.

本文言語英語
ページ(範囲)78-82
ページ数5
ジャーナルAngewandte Chemie - International Edition
42
1
DOI
出版ステータス出版済み - 1 3 2003
外部発表はい

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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