Phenylene-Bridged Expanded Porphyrazines

Fumiya Iizuka, Yuto Kage, Nagao Kobayashi, Hiroyuki Furuta, Soji Shimizu

研究成果: ジャーナルへの寄稿記事

2 引用 (Scopus)

抄録

Novel expanded porphyrazines comprising o- and p-phenylene units were synthesized from self-condensation reactions of acyclic [2+1]-type precursors prepared from 1,3-diiminoisoindoline and the corresponding phenylenediamines. Möbius and Hückel topological structures of [4+2]-type and [3+2]-type expanded porphyrazines, respectively, were elucidated by X-ray crystallography. Despite the Möbius and Hückel [4n]π-electron systems, these expanded porphyrazines are virtually nonaromatic as a result of their flexible structures in solution, which may diminish intrinsic aromaticity and antiaromaticity.

元の言語英語
ページ(範囲)1021-1024
ページ数4
ジャーナルChemPlusChem
82
発行部数7
DOI
出版物ステータス出版済み - 8 1 2017

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Phenylenediamines
Condensation reactions
Flexible structures
X ray crystallography
Electrons

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

これを引用

Phenylene-Bridged Expanded Porphyrazines. / Iizuka, Fumiya; Kage, Yuto; Kobayashi, Nagao; Furuta, Hiroyuki; Shimizu, Soji.

:: ChemPlusChem, 巻 82, 番号 7, 01.08.2017, p. 1021-1024.

研究成果: ジャーナルへの寄稿記事

Iizuka, F, Kage, Y, Kobayashi, N, Furuta, H & Shimizu, S 2017, 'Phenylene-Bridged Expanded Porphyrazines', ChemPlusChem, 巻. 82, 番号 7, pp. 1021-1024. https://doi.org/10.1002/cplu.201600482
Iizuka, Fumiya ; Kage, Yuto ; Kobayashi, Nagao ; Furuta, Hiroyuki ; Shimizu, Soji. / Phenylene-Bridged Expanded Porphyrazines. :: ChemPlusChem. 2017 ; 巻 82, 番号 7. pp. 1021-1024.
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