Photo-cleavage of cobalt-carbon bonds of alkylcobalt(III) complexes by iodine with large quantum yields

Shunichi Fukuzumi; Tatsushi Goto; Kunio Ishikawa; Toshio Tanaka

doi:10.1039/C39890000260

Photo-cleavage of cobalt-carbon bonds of alkylcobalt(III) complexes by iodine with large quantum yields

Shunichi Fukuzumi, Tatsushi Goto, Kunio Ishikawa, Toshio Tanaka

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

2 被引用数 (Scopus)

抄録

Cobalt-carbon bonds of alkylcobalt(III) complexes are readily cleaved by iodine in carbon tetrachloride to yield alkyl iodides via photoinduced electron-transfer radical chain reactions with large quantum yields (e.g., Φ = 7.0 × 10³) under low energy irradiation (λ 509 nm).

本文言語	英語
ページ（範囲）	260-261
ページ数	2
ジャーナル	Journal of the Chemical Society, Chemical Communications
号	4
DOI	https://doi.org/10.1039/C39890000260
出版ステータス	出版済み - 1月 1 1989
外部発表	はい

All Science Journal Classification (ASJC) codes

分子医療

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10.1039/C39890000260

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title = "Photo-cleavage of cobalt-carbon bonds of alkylcobalt(III) complexes by iodine with large quantum yields",

abstract = "Cobalt-carbon bonds of alkylcobalt(III) complexes are readily cleaved by iodine in carbon tetrachloride to yield alkyl iodides via photoinduced electron-transfer radical chain reactions with large quantum yields (e.g., Φ = 7.0 × 103) under low energy irradiation (λ 509 nm).",

author = "Shunichi Fukuzumi and Tatsushi Goto and Kunio Ishikawa and Toshio Tanaka",

year = "1989",

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T1 - Photo-cleavage of cobalt-carbon bonds of alkylcobalt(III) complexes by iodine with large quantum yields

AU - Fukuzumi, Shunichi

AU - Goto, Tatsushi

AU - Ishikawa, Kunio

AU - Tanaka, Toshio

PY - 1989/1/1

Y1 - 1989/1/1

N2 - Cobalt-carbon bonds of alkylcobalt(III) complexes are readily cleaved by iodine in carbon tetrachloride to yield alkyl iodides via photoinduced electron-transfer radical chain reactions with large quantum yields (e.g., Φ = 7.0 × 103) under low energy irradiation (λ 509 nm).

AB - Cobalt-carbon bonds of alkylcobalt(III) complexes are readily cleaved by iodine in carbon tetrachloride to yield alkyl iodides via photoinduced electron-transfer radical chain reactions with large quantum yields (e.g., Φ = 7.0 × 103) under low energy irradiation (λ 509 nm).

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Photo-cleavage of cobalt-carbon bonds of alkylcobalt(III) complexes by iodine with large quantum yields

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