Photocatalytic alkene reduction by a B12-TiO2 hybrid catalyst coupled with C-F bond cleavage for

Gem -difluoroolefin synthesis

研究成果: ジャーナルへの寄稿記事

9 引用 (Scopus)

抄録

Photocatalytic syntheses of gem-difluoroolefins were performed using the B12-TiO2 hybrid catalyst during the CC bond reduction of α-trifluoromethyl styrenes with C-F bond cleavage at room temperature under nitrogen. The gem-difluoroolefins were used as synthetic precursors for fluorinated cyclopropanes.

元の言語英語
ページ(範囲)9478-9481
ページ数4
ジャーナルChemical Communications
53
発行部数68
DOI
出版物ステータス出版済み - 2017

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Gems
Alkenes
Olefins
Styrenes
Cyclopropanes
Catalysts
Styrene
Nitrogen
Temperature

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

これを引用

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title = "Photocatalytic alkene reduction by a B12-TiO2 hybrid catalyst coupled with C-F bond cleavage for: Gem -difluoroolefin synthesis",
abstract = "Photocatalytic syntheses of gem-difluoroolefins were performed using the B12-TiO2 hybrid catalyst during the CC bond reduction of α-trifluoromethyl styrenes with C-F bond cleavage at room temperature under nitrogen. The gem-difluoroolefins were used as synthetic precursors for fluorinated cyclopropanes.",
author = "Hui Tian and Hisashi Shimakoshi and Kenji Imamura and Yoshihito Shiota and Kazunari Yoshizawa and Yoshio Hisaeda",
year = "2017",
doi = "10.1039/c7cc04377e",
language = "English",
volume = "53",
pages = "9478--9481",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
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T1 - Photocatalytic alkene reduction by a B12-TiO2 hybrid catalyst coupled with C-F bond cleavage for

T2 - Gem -difluoroolefin synthesis

AU - Tian, Hui

AU - Shimakoshi, Hisashi

AU - Imamura, Kenji

AU - Shiota, Yoshihito

AU - Yoshizawa, Kazunari

AU - Hisaeda, Yoshio

PY - 2017

Y1 - 2017

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AB - Photocatalytic syntheses of gem-difluoroolefins were performed using the B12-TiO2 hybrid catalyst during the CC bond reduction of α-trifluoromethyl styrenes with C-F bond cleavage at room temperature under nitrogen. The gem-difluoroolefins were used as synthetic precursors for fluorinated cyclopropanes.

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DO - 10.1039/c7cc04377e

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