Photocatalytic decomposition of acetaldehyde in air over titanium dioxide

Jian Hua Xu, Fumihide Shiraishi

研究成果: Contribution to journalArticle査読

22 被引用数 (Scopus)

抄録

The photocatalytic decomposition of acetaldehyde in air at initial concentrations ranging from 3 to 200 mg m-3 has been studied in a semitransparent closed box with an inlet volume of 0.056 m3. The photocatalytic reactors consisted of a glass tube, 250 mm long with inside diameters of 28, 35, or 45 mm, whose inner surface was coated with a thin film of titanium dioxide, and a 6-W blacklight fluorescent lamp located at the axis of the glass tube. The decomposition of acetaldehyde was almost complete within 1-3 h and its main product was carbon dioxide. A kinetic study showed that the photocatalytic reaction obeys a Langmuir adsorption isotherm. Although the light intensity was certainly decreased with the distance from the light source, the degree of this decrease was much smaller than the degree of the decrease in the kinetic constants, which suggests that the light intensity is not simply proportional to the degree of the photo-excitation of TiO2 and the rate of the resulting photocatalytic decomposition of acetaldehyde.

本文言語英語
ページ(範囲)1096-1100
ページ数5
ジャーナルJournal of Chemical Technology and Biotechnology
74
11
DOI
出版ステータス出版済み - 11 1 1999
外部発表はい

All Science Journal Classification (ASJC) codes

  • バイオテクノロジー
  • 化学工学(全般)
  • 再生可能エネルギー、持続可能性、環境
  • 燃料技術
  • 廃棄物管理と処理
  • 汚染
  • 有機化学
  • 無機化学

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