Photochemical H2 evolution catalyzed by porphyrin-based cubic cages singly and doubly encapsulating PtCl2 (4,4'-dimethyl-2,2'-bipyridine)

Shota Tanaka, Takashi Nakazono, Kosei Yamauchi, Ken Sakai

研究成果: Contribution to journalArticle査読

2 被引用数 (Scopus)

抄録

A porphyrin-based cubic cage (Cube) was reacted with a Pt(II)-based molecular H2-evolving catalyst, PtCl2 (dmbpy) (PtDmb; dmbpy: 4,4'-dimethyl-2,2'-bipyridine), to give Cubes incorporated with one or two equivalents of PtDmb, i.e., Cube(PtDmb) and Cube(PtDmb) 2, which was confirmed by ESI-TOF MS spectroscopy. A photochemical H2-evolving system consisting of EDTA (sacrificial electron donor), [Ru(bpy)3]2+ (photosensitizer), and methylviologen (electron relay) was used to demonstrate that the catalyst encapsulated can also serve as an effective H2-evolving catalyst.

本文言語英語
ページ(範囲)1573-1575
ページ数3
ジャーナルChemistry Letters
46
10
DOI
出版ステータス出版済み - 2017

All Science Journal Classification (ASJC) codes

  • 化学 (全般)

フィンガープリント

「Photochemical H<sub>2</sub> evolution catalyzed by porphyrin-based cubic cages singly and doubly encapsulating PtCl<sub>2</sub> (4,4'-dimethyl-2,2'-bipyridine)」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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